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聚二甲基硅氧烷表面改性及其对牛奶润滑特性评估的影响
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国家自然科学基金项目(51675297;31901817);摩擦学国家重点实验室开放基金项目(SKLTKF19B16;SKLTKF20B12)


Surface Modification of Polydimethylsiloxane and Its Effect on Evaluation of Milk Lubricating Properties 
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    摘要:

    口腔摩擦学是食品口感研究的重要问题。针对模拟口腔材料聚二甲基硅氧烷(PDMS)与真实口腔表面亲水性的差异,对PDMS表面进行紫外臭氧辐照(UVO)处理,研究PDMS表面改性的效果及对牛奶润滑特性评估的影响。利用接触角测量仪、XPS分析仪、激光共聚焦显微镜分别表征了PDMS表面宏观亲水性、表面微观化学成分、表面形貌,采用微摩擦磨损试验机评估不同脂肪含量牛奶的润滑特性,并分析PDMS表面物理化学性质对牛奶润滑特性影响机制。结果表明:PDMS表面UVO处理1和4 h,接触角由110°分别降至82°和60°,PDMS表面氧硅原子比升高,且形成玻璃态SiOx薄膜;PDMS摩擦副表面性质会影响摩擦性能,其中亲水PDMS表面的摩擦因数大于疏水PDMS表面,这是因为UVO处理后的PDMS表面亲水性提高,但表面粗糙度增大,增大了蛋白质黏附强度;脱脂牛奶的摩擦因数高于全脂牛奶,这是因为牛奶中脂肪含量下降影响流体润滑成膜,导致摩擦因数增加。研究结果有助于理解乳制品口感形成机制,为食品口感的体外综合评价提供参考。

    Abstract:

    Studies of “oral tribology” have attracted growing interests in food industry.However,there is a problem that the properties of the simulated oral material,the poly dimethylsiloxane (PDMS) is obviously different from the real oral surface.The ultraviolet/Ozone treatment was employed for PDMS surface modification,and the influences of PDMS surface properties on the evaluation of milk lubrication properties was investigated.The hydrophilicity,surface compositions and surface topography were characterized with contact angle goniometer,X-ray photoelectron spectroscopy (XPS) and Confocal laser scanning microscope (CLSM) respectively to identify changes of physical and chemical properties of PDMS surface.The tribological measurement was carried out on the UMT-3 tribometer to evaluate lubrication properties of milk with different fat content,and analyze the influence mechanism of surface physical and chemical properties of PDMS on milk lubrication characteristics.The results show that after UVO treatment for 1 h and 4 h,the contact angle is decreased from 110° to 82° and 60° respectively.The atomic ratio of oxygen vs.silicon on the PDMS surface is increased,and a glass-like SiOx film is formed to increase the hydrophilicity.The surface properties of the PDMS friction pair will affect the tribological performance.Among them,the coefficient of friction (COF) of the hydrophilic PDMS surface is higher than that of the hydrophobic PDMS surface.This is because the hydrophilicity of the PDMS surface after UVO treatment is improved,but the surface roughness increases,adhesion strength of the protein is increased.The COF of skimmed milk is higher than that of whole milk.This is because the decrease in fat content will affect fluid lubrication and film formation,resulting in an increase in COF.The study contributes to better understand the mechanism of milk textural sensation and systematic ex vivo evaluation of food taste.

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张紫铜,黄雅婷,李连良,王巍琦.聚二甲基硅氧烷表面改性及其对牛奶润滑特性评估的影响[J].润滑与密封,2022,47(3):74-80.
ZHANG Zitong, HUANG Yating, LI Lianliang, WANG Weiqi. Surface Modification of Polydimethylsiloxane and Its Effect on Evaluation of Milk Lubricating Properties [J]. Lubrication Engineering,2022,47(3):74-80.

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  • 在线发布日期: 2022-05-20
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